Transistor and semiconductor device

ABSTRACT

Manufactured is a transistor including an oxide semiconductor layer, a source electrode layer and a drain electrode layer overlapping with part of the oxide semiconductor layer, a gate insulating layer overlapping with the oxide semiconductor layer, the source electrode layer, and the drain electrode layer, and a gate electrode overlapping with part of the oxide semiconductor layer with the gate insulating layer provided therebetween, wherein, after the oxide semiconductor layer which is to be a channel formation region is irradiated with light and the light irradiation is stopped, a relaxation time of carriers in photoresponse characteristics of the oxide semiconductor layer has at least two kinds of modes: τ 1  and τ 2 , τ 1 &lt;τ 2  is satisfied, and τ 2  is 300 seconds or less. In addition, a semiconductor device including the transistor is manufactured.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a transistor and a semiconductor deviceat least part of which includes the transistor.

Note that in this specification, a semiconductor device means any devicethat can function by utilizing semiconductor characteristics. Anelectro-optical device such as a liquid crystal display device or alight-emitting device, a semiconductor circuit, and an electronic deviceare all semiconductor devices.

2. Description of the Related Art

Although transistors including silicon semiconductors have been used forconventional display devices typified by liquid crystal televisions,oxide semiconductors have attracted attention as a material whichreplaces silicon semiconductors. For example, an active matrix displaydevice in which an amorphous oxide containing In, Ga, and Zn is used foran active layer of a transistor and the electron carrier concentrationof the amorphous oxide is lower than 10¹⁸/cm³ is disclosed (see PatentDocument 1).

However, some problems of a transistor formed using an oxidesemiconductor have been pointed out. One of the problems is stability ofcharacteristics, and it is pointed out that electrical characteristicsare changed by irradiation with visible light or ultraviolet light(e.g., see Non-Patent Document 1).

REFERENCE Patent Document

-   [Patent Document 1] Japanese Published Patent Application No.    2006-165528

Non-Patent Document

-   [Non-Patent Document 1] Dong Hee Lee, Ken-ichi Kawamura, Kenji    Nomura, Hiroshi Yanagi, Toshio Kamiya, Masahiro Hirano, and Hideo    Hosono, “Steady-state photoconductivity of amorphous In—Ga—Zn—O”,    Thin Solid Films, Vol. 518, pp. 3000-3003 (2010).

SUMMARY OF THE INVENTION

An oxide semiconductor formed using a metal oxide has a band gap ofapproximately 3 eV and originally transmits visible light. However, itis known that a film formed using the oxide semiconductor deteriorateswhen being irradiated with intense light (the deterioration is calledlight deterioration).

Any method for improving such a change in the characteristics caused bylight in a transistor including an oxide semiconductor has not beenproposed, which causes a delay in practical use of the oxidesemiconductor which is expected as a new material.

In addition, in a liquid crystal display device in which a backlight isused, a transistor including an oxide semiconductor is irradiated withlight from the backlight in some cases. In such a case, leakage currentmight be generated by photoexcitation even in an off state of thetransistor, which leads to reduction in display quality or lightdeterioration.

An object of one embodiment of the present invention is to provide atransistor in which light deterioration is suppressed as much aspossible and electrical characteristics are stable, and a semiconductordevice including the transistor.

A mechanism of generation of photoelectric current due to irradiating anoxide semiconductor layer with light will be described below.

Carriers in a semiconductor can be expressed by continuity equationsshown in Formula 1 and Formula 2.

$\begin{matrix}{\frac{n}{t} = {{\frac{1}{q}\frac{\partial J_{n}}{\partial x}} + \left( {G_{n} - R_{n}} \right)}} & \left\lbrack {{Formula}\mspace{14mu} 1} \right\rbrack \\{\frac{p}{t} = {{{- \frac{1}{q}}\frac{\partial J_{p}}{\partial x}} + \left( {G_{p} - R_{p}} \right)}} & \left\lbrack {{Formula}\mspace{14mu} 2} \right\rbrack\end{matrix}$

In the above two formulas, t represents time, x represents position, andq represents charge. Here, n represents carrier concentration ofelectrons, p represents carrier concentration of holes, J_(n) representsa current value of electrons, J_(p) represents a current value of holes,G_(n) represents a generation probability of electrons, G_(p) representsa generation probability of holes, R_(n) represents a probability ofrecombination, and R_(p) represents a probability of recombination. Whenthe carrier concentration of holes is divided into a carrierconcentration of holes p₀ in a thermal equilibrium state and adifference of carrier concentration of holes Δp from the thermalequilibrium state, the carrier concentration of holes can be expressedby Formula 3.

p=p ₀ +Δp  [Formula 3]

When a semiconductor is irradiated with light having an energy ofgreater than or equal to the band gap and absorbs the light, electronsin the valence band are transferred to the conduction band and holes aregenerated. When the generation probability of holes is represented byG_(0p), the probability of recombination is expressed by Formula 4.Here, τ_(p) represents a relaxation time of holes generated.

$\begin{matrix}{R = {\frac{p}{\tau_{p}} = {\frac{p_{0}}{\tau_{p}} + \frac{\Delta \; p}{\tau_{p}}}}} & \left\lbrack {{Formula}\mspace{14mu} 4} \right\rbrack\end{matrix}$

Suppose that diffusing light in a source direction or a drain directioncan be ignored when a device is uniformly irradiated with light, acontinuity equation represented by Formula 5 is obtained.

$\begin{matrix}{\frac{\left( {\Delta \; p} \right)}{t} = {{G_{op} - R} = {G_{op} - \frac{\Delta \; p}{\tau_{p}}}}} & \left\lbrack {{Formula}\mspace{14mu} 5} \right\rbrack\end{matrix}$

When Formula 5 is solved under the condition that an initialphotoelectric current value is 0, the carrier concentration is expressedby Formula 6.

$\begin{matrix}{{\Delta \; {p(t)}} = {G_{op}{\tau_{p}\left\lbrack {1 - {\exp \left( {- \frac{t}{\tau_{p}}} \right)}} \right\rbrack}}} & \left\lbrack {{Formula}\mspace{14mu} 6} \right\rbrack\end{matrix}$

When the time at which a light source is turned off is represented byt₀, the carrier concentration is expressed by Formula 7.

$\begin{matrix}{{\Delta \; {p(t)}} = {\Delta \; {p\left( t_{0} \right)}{\exp \left( {- \frac{t - t_{0}}{\tau_{p}}} \right)}\left( {t \geq t_{0}} \right)}} & \left\lbrack {{Formula}\mspace{14mu} 7} \right\rbrack\end{matrix}$

Since the photoelectric current is in proportion to excess carrierconcentration, the current formula is expressed by Formula 8.

$\begin{matrix}{{I(t)} = \left\{ \begin{matrix}{{I_{0}\left\lbrack {1 - {\exp \left( {- \frac{t}{\tau_{p}}} \right)}} \right\rbrack}\left( {0 \leq t \leq t_{0}} \right)} \\{{I_{0}\left\lbrack {1 - {\exp \left( {- \frac{t_{0}}{\tau_{p}}} \right)}} \right\rbrack}{\exp \left( {- \frac{t - t_{0}}{\tau_{p}}} \right)}\left( {t \geq t_{0}} \right)}\end{matrix} \right.} & \left\lbrack {{Formula}\mspace{14mu} 8} \right\rbrack\end{matrix}$

(I₀ is a constant, which depends on physical property and structure.)

The relaxation time τ depends on a model of carrier recombination. Thereare basically two types of recombination processes: direct recombinationand indirect recombination (SRH recombination).

Further, there are traps that can trap holes easily but cannot trapelectrons easily and where recombination hardly occurs. Such a trap iscalled a “safe” trap in this specification.

FIG. 3A is a schematic diagram of the “safe” trap. FIG. 3B is aschematic diagram showing a transition due to heat after trapping.

Since the energy position of the “safe” trap is closer to the valenceband than the intrinsic Fermi level and an electron is not easilytrapped by the “safe” trap, some holes trapped by the “safe” traps canbe transferred to the valence band by heat and thus contribute toelectric conduction. The relaxation time in photoresponsecharacteristics (photoresponse characteristics of current) of asemiconductor having the “safe” trap exhibits at least two kinds ofmodes τ₁ and τ₂).

One embodiment of the present invention disclosed in this specificationis a transistor including an oxide semiconductor layer; a sourceelectrode layer and a drain electrode layer overlapping with part of theoxide semiconductor layer; a gate insulating layer overlapping with theoxide semiconductor layer, the source electrode layer, and the drainelectrode layer; and a gate electrode overlapping with part of the oxidesemiconductor layer with the gate insulating layer providedtherebetween, wherein, after the oxide semiconductor layer which is tobe a channel formation region is irradiated with light and the lightirradiation is stopped, a relaxation time of carriers in photoresponsecharacteristics of the oxide semiconductor layer has at least two kindsof modes: τ₁ and τ₂, τ₁<τ₂ is satisfied, and τ₂ is 300 seconds or less.

Another embodiment of the present invention disclosed in thisspecification is a semiconductor device including a transistor wherein,after an oxide semiconductor layer which is to be a channel formationregion is irradiated with light and the light irradiation is stopped, arelaxation time of carriers in photoresponse characteristics of theoxide semiconductor layer has at least two kinds of modes: τ₁ and τ₂,τ₁<τ₂ is satisfied, and τ₂ is 300 seconds or less.

The existence of the two kinds of modes (τ₁ and τ₂) of the relaxationtime in photoresponse characteristics can be confirmed by the existenceof two regions in results of changes in photoelectric current over time,that is, a region where the current value falls rapidly and a regionwhere the current value falls slowly, when the average time τ₁ taken fortrapping of carriers by “safe” traps is long enough.

Considering the “safe” trap, the current formula after τ₁ is expressedby Formula 9. Note that τ₂ represents an average time during whichcarriers stay at the “safe” trap.

$\begin{matrix}{{I(t)} = {A\; {\tau_{p}\left( {\frac{D_{e}}{D_{h}} \cdot \frac{\tau_{2}}{\tau_{1}}} \right)}{\exp \left( {- \frac{t}{\tau_{2}}} \right)}\left( {t \geq t_{1}} \right)}} & \left\lbrack {{Formula}\mspace{14mu} 9} \right\rbrack\end{matrix}$

A: constant depending on physical property or temperatureD_(e), D_(h): diffusion coefficient of electron and diffusioncoefficient of holeτ_(p): relaxation time of hole in thermal equilibrium

According to one embodiment of the present invention, it is possible toprovide a transistor which hardly deteriorates owing to lightirradiation and has stable electrical characteristics and asemiconductor device including the transistor.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a graph showing photoresponse characteristics of an oxidesemiconductor.

FIG. 2 is a graph in which a region in the range of 0 sec to 100 sec inFIG. 1 is enlarged.

FIGS. 3A and 3B are schematic diagrams of a “safe” trap.

FIGS. 4A and 4B are cross-sectional views each illustrating a structureof a transistor.

FIGS. 5A to 5D are cross-sectional views illustrating a process formanufacturing a transistor.

FIG. 6 is a graph showing a method for estimating

FIGS. 7A and 7B are a cross-sectional view and a top view illustratingan element.

FIG. 8 is a conceptual diagram of a measurement system for examinationof photoresponse characteristics.

FIG. 9 is a graph showing a wavelength spectrum of a white LED.

FIG. 10 is a graph showing a wavelength spectrum of light after passingthrough an optical filter.

FIG. 11 is a graph showing photoresponse characteristics of transistors.

FIG. 12 is a graph in which a region in the range of 0 sec to 300 sec inFIG. 11 is enlarged.

FIG. 13 is a graph showing changes in threshold voltages of transistorsafter negative BT treatment under light.

FIG. 14 is a diagram for describing band models of an In—Ga—Zn—Osemiconductor.

FIG. 15A illustrates an electronic device and FIG. 15B is a blockdiagram of the electronic device.

FIGS. 16A to 16F illustrate electronic devices.

DETAILED DESCRIPTION OF THE INVENTION

Hereinafter, embodiments of the present invention will be described indetail with reference to the accompanying drawings. However, the presentinvention is not limited to the description below, and it is easilyunderstood by those skilled in the art that modes and details disclosedherein can be modified in various ways without departing from the spiritand the scope of the present invention. Therefore, the present inventionis not construed as being limited to description of the embodiments.

Embodiment 1

In this embodiment, photoresponse characteristics of elements eachincluding an oxide semiconductor will be described.

First, each of the elements having a structure illustrated in FIGS. 7Aand 7B is manufactured in order to evaluate a single film of an oxidesemiconductor. FIG. 7A is a cross-sectional view of the element in whichan oxide semiconductor film 102, a first electrode 103, and a secondelectrode 104 are formed over a glass substrate 101. In addition, aninsulating layer 105 is formed over the oxide semiconductor film 102,thereby suppressing variation in electrical characteristics of the oxidesemiconductor film 102 due to being in contact with the outside air fora long time. FIG. 7B illustrates a top surface shape of the elementincluding the first electrode 103 and the second electrode 104 in aregion of 4.8 mm×6 mm, and a regular gap is provided between the firstelectrode 103 and the second electrode 104. The width of the gap is 0.2mm, the length is 32.7 mm, and the thickness of the oxide semiconductorfilm 102 formed in a region under the gap is 25 nm. In addition, thethickness of the oxide semiconductor film 102 in the other region is 50nm.

A method for manufacturing each element is as follows.

First, an In—Ga—Zn—O film with a thickness of 50 nm is formed as theoxide semiconductor film 102 over a glass substrate (126.6 mm×126.6 mm).The In—Ga—Zn—O film is formed by a sputtering method using an oxidetarget having a composition ratio of In₂O₃:Ga₂O₃:ZnO=1:1:1 [molarratio]. Conditions for the film formation are as follows: thetemperature of the film formation is room temperature, the flow rate ofargon is 10 sccm, the flow rate of oxygen is 5 sccm, the pressure is 0.4Pa, and the power is 500 W.

Then, heat treatment is performed at 450° C. for 1 hour in a nitrogenatmosphere. This heat treatment is performed in an atmosphere of aninert gas such as nitrogen, helium, neon, or argon, which does notcontain water, hydrogen, or the like. Here, the dew point of theatmosphere gas is preferably −40° C. or lower, more preferably −60° C.or lower. In addition, an inert gas such as nitrogen, helium, neon, orargon which is introduced into a heat treatment apparatus preferably hasa purity of 6N (99.9999%) or higher, more preferably 7N (99.99999%) orhigher (that is, the concentration of impurities is 1 ppm or lower,preferably 0.1 ppm or lower).

After the heat treatment, a layered conductive film is formed bystacking a titanium nitride film with a thickness of 50 nm, a titaniumfilm with a thickness of 50 nm, an aluminum film with a thickness of 200nm, and a titanium film with a thickness of 50 nm by a sputteringmethod.

A resist mask is formed over the layered conductive film through aphotolithography step, and etching is performed selectively to form thefirst electrode 103 and the second electrode 104. After that, O₂ ashingis performed and the resist mask is removed. By this etching step, aregion of the oxide semiconductor film 102 where the conductive film isremoved is also etched, but the etching time is adjusted so that thethickness of the region is 25 nm.

Next, by a sputtering method using a silicon oxide target, a siliconoxide film with a thickness of 300 nm is formed over the oxidesemiconductor film 102, the first electrode 103, and the secondelectrode 104.

Then, a resist mask is formed over the silicon oxide film through aphotolithography step, and etching is performed selectively to form theinsulating layer 105. After that, heat treatment is performed at 250° C.for 1 hour in a nitrogen atmosphere, so that the element is completed.

Next, results of examination of photoresponse characteristics of theelements will be described. Note that the number of the elementsprepared is three and light irradiation is performed while heating theelements at respective temperatures of 25° C., 85° C., and 150° C.Behaviors of current values before and after the light irradiation areexamined.

As a light source of the light with which the oxide semiconductor film102 is irradiated, a white LED (MDBL-CW100 produced by MoritexCorporation) is used. The wavelength spectrum of this white LED is shownin FIG. 9. Irradiation with this white light at 17000 cd/cm² isperformed for 600 seconds. Then, the time when this light source isturned off is set at 0, and current values are measured. FIG. 1 is agraph showing the photoresponse characteristics. In FIG. 1, thehorizontal axis indicates time and the vertical axis indicates a currentvalue. FIG. 2 is a graph in which a region in the range of 0 sec to 100sec in FIG. 1 is enlarged, the current value is normalized, and thevertical axis is a log scale.

Here, it is found that the graph of the photoresponse characteristicshas a time (τ₁) during which photoelectric current is reduced rapidlyand a time (τ₂) during which the photoelectric current is reduced slowlyafterwards. As shown in FIG. 6, τ₁ is estimated with the intersectionpoint of the inclination of the rapidly reduced photoelectric currentand the inclination of the photoelectric current in τ₂. In addition, τ₂is estimated with the current formula expressed by Formula 9.

Note that τ₁ is calculated with the inclination between time 0 [sec] andtime 1 [sec]. This is because the temporal resolution is 1 [sec] atmeasurement of current in order to increase the accuracy of themeasurement. Thus, sharpness around time 0 [sec] right after the lightsource is turned off cannot be correctly measured, and τ₁ might beestimated to be larger than the real value. Table 1 shows τ₁ and τ₂ ateach of the temperatures.

TABLE 1 25° C. 85° C. 150° C. τ₁ [sec] 2.3 1.6 1.5 τ₂ [sec] 350 480 340

Considering the temporal resolution at the measurement, τ₁ can beregarded as being substantially the same among the temperatures and τ₂can be regarded as being substantially the same among the temperatures.The above results can also be led by dependence of τ₁ and τ₂ on thedensity of traps. Meanwhile, FIG. 2 indicates that the ratio of acurrent value after a sufficient time passes after light irradiation isstopped (for example, time 60 [sec]) with respect to a current valueright after the light irradiation is stopped (time 0 [sec]) is larger asthe temperature is higher. This is because the probability of repeatedthermal excitation from the traps is higher as the temperature ishigher.

The reason why the graph of the photoresponse characteristics has suchinclination in two stages with respect to the time axis is that “safe”traps exist close to a conduction band or a valence band.

Next, photoresponse characteristics of transistors each including anoxide semiconductor layer which is similar to the oxide semiconductorlayer in the above element will be described.

Structures of the transistors used for comparison of photoresponsecharacteristics are of two kinds: a bottom-gate structure illustrated inFIG. 4A and a top-gate structure illustrated in FIG. 4B. Anotherbottom-gate transistor without heat treatment of an oxide semiconductorlayer, which is described below, is also prepared. Thus, photoresponsecharacteristics of three transistors in total are compared.

A transistor 310 illustrated in FIG. 4A is a bottom-gate transistor. Thetransistor 310 includes, over a substrate 400 having an insulatingsurface, a gate electrode layer 301, a gate insulating layer 302, anoxide semiconductor layer 303, a source electrode layer 305 a, and adrain electrode layer 305 b. The transistor 310 is covered with aninsulating layer 307 which is in contact with the oxide semiconductorlayer 303. In this embodiment, a tungsten layer with a thickness of 100nm is used as the gate electrode layer 301; a silicon oxynitride layerwith a thickness of 100 nm formed by a high density plasma CVD method isused as the gate insulating layer 302; an In—Ga—Zn—O film with athickness of 25 nm is used as the oxide semiconductor layer 303; a stackof a titanium layer with a thickness of 100 nm, an aluminum layer with athickness of 200 nm, and a titanium layer with a thickness of 100 nm isused as the source electrode layer 305 a and the drain electrode layer305 b; and a silicon oxide layer with a thickness of 300 nm is used asthe insulating layer 307.

A transistor 440 illustrated in FIG. 4B is a top-gate transistor. Thetransistor 440 includes, over the substrate 400 having an insulatingsurface, an insulating layer 437, an oxide semiconductor layer 403, asource electrode layer 405 a, a drain electrode layer 405 b, a gateinsulating layer 402, and a gate electrode layer 401. The transistor 440is covered with an insulating layer 407. In this embodiment, a siliconoxide layer with a thickness of 300 nm is used as the insulating layer437; an In—Ga—Zn—O film with a thickness of 30 nm is used as the oxidesemiconductor layer 403; a tungsten layer with a thickness of 100 nm isused as the source electrode layer 405 a and the drain electrode layer405 b; a silicon oxynitride layer with a thickness of 100 nm formed by aplasma CVD method is used as the gate insulating layer 402; a stack of atantalum nitride layer with a thickness of 30 nm and a tungsten layerwith a thickness of 370 nm is used as the gate electrode layer 401; anda silicon oxide layer with a thickness of 300 nm is used as theinsulating layer 407.

Although not illustrated, a protective insulating layer may be formedover the insulating layer 307 of the transistor 310 and the insulatinglayer 407 of the transistor 440.

Further, the transistor may have a single gate structure including onechannel formation region or a multi-gate structure such as a double gatestructure including two channel formation regions or a triple gatestructure including three channel formation regions. Furthermore, thetransistor may have a dual gate structure including two gate electrodelayers positioned over and below a channel region with a gate insulatinglayer provided therebetween.

In this embodiment, the size of the transistors is as follows regardlessof the structure. The channel length is 3 μm, and the channel width is50 μm.

Next, with reference to FIGS. 5A to 5D, an example of a method formanufacturing the transistor 440 will be described. Note that thetransistor 310 can be manufactured using similar material and method.

First, the insulating layer 437 which serves as a base film is formedover the substrate 400 having an insulating surface. The insulatinglayer 437 has a function of preventing impurity elements in thesubstrate 400 from diffusing and can be formed using silicon nitridefilm, a silicon oxide film, a silicon nitride oxide film, a siliconoxynitride film, or a film of aluminum oxide, gallium oxide, or galliumaluminum oxide represented by Ga_(x)Al_(2-x)O_(3+y) (0≦x≦2, y>0, x isgreater than or equal to 0 and less than or equal to 2, and y is greaterthan 0). The structure of the base film is not limited to a single-layerstructure, and may be a layered structure of a plurality of the abovefilms.

Here, a substrate having heat resistance enough to withstand at leastheat treatment performed later can be used as the substrate 400. Forexample, a glass substrate of barium borosilicate glass,aluminoborosilicate glass, or the like, a ceramic substrate, a quartzsubstrate, or a sapphire substrate can be used. A single crystalsemiconductor substrate or a polycrystalline semiconductor substratemade of silicon, silicon carbide, or the like; a compound semiconductorsubstrate made of silicon germanium or the like; an SOI substrate; orthe like may be used as the substrate 400.

A flexible substrate may be used as the substrate 400. In the case wherea flexible substrate is used, the following methods can be given, andeither of them may be used: a method in which a transistor including anoxide semiconductor layer is directly formed over a flexible substrate;and a method in which a transistor including an oxide semiconductorlayer is formed over another substrate and is transferred to a flexiblesubstrate. In the case where the method in which the transistor istransferred to a flexible substrate is employed, the substrate overwhich the transistor is formed may be provided with a separation layer.

Next, an oxide semiconductor film having a thickness of greater than orequal to 2 nm and less than or equal to 200 nm, preferably greater thanor equal to 5 nm and less than or equal to 30 nm is formed over theinsulating layer 437.

An oxide semiconductor used for the oxide semiconductor film includes atleast one element selected from In, Ga, Sn, Zn, Al, Mg, Hf, andlanthanoid. For example, any of the following oxide semiconductors canbe used: a four-component metal oxide such as an In—Sn—Ga—Zn—O-basedoxide semiconductor; a three-component metal oxide such as anIn—Ga—Zn—O-based oxide semiconductor, an In—Sn—Zn—O-based oxidesemiconductor, an In—Al—Zn—O-based oxide semiconductor, aSn—Ga—Zn—O-based oxide semiconductor, an Al—Ga—Zn—O-based oxidesemiconductor, a Sn—Al—Zn—O-based oxide semiconductor, anIn—Hf—Zn—O-based oxide semiconductor, an In—La—Zn—O-based oxidesemiconductor, an In—Ce—Zn—O-based oxide semiconductor, anIn—Pr—Zn—O-based oxide semiconductor, an In—Nd—Zn—O-based oxidesemiconductor, an In—Pm—Zn—O-based oxide semiconductor, anIn—Sm—Zn—O-based oxide semiconductor, an In—Eu—Zn—O-based oxidesemiconductor, an In—Gd—Zn—O-based oxide semiconductor, anIn—Tb—Zn—O-based oxide semiconductor, an In—Dy—Zn—O-based oxidesemiconductor, an In—Ho—Zn—O-based oxide semiconductor, anIn—Er—Zn—O-based oxide semiconductor, an In—Tm—Zn—O-based oxidesemiconductor, an In—Yb—Zn—O-based oxide semiconductor, or anIn—Lu—Zn—O-based oxide semiconductor; a two-component metal oxide suchas an In—Zn—O-based oxide semiconductor, a Sn—Zn—O-based oxidesemiconductor, an Al—Zn—O-based oxide semiconductor, a Zn—Mg—O-basedoxide semiconductor, a Sn—Mg—O-based oxide semiconductor, anIn—Mg—O-based oxide semiconductor, or an In—Ga—O-based oxidesemiconductor; an In—O-based oxide semiconductor; a Sn—O-based oxidesemiconductor; a Zn—O-based oxide semiconductor; and the like. Further,SiO₂ may be contained in the above oxide semiconductor. Here, anIn—Ga—Zn—O-based oxide semiconductor means an oxide containing indium(In), gallium (Ga), and zinc (Zn), and there is no particular limitationon the composition ratio thereof. Further, the In—Ga—Zn—O-based oxidesemiconductor may contain an element other than In, Ga, and Zn.

As the oxide semiconductor film, a film of a material represented by achemical formula 1 nMO₃(ZnO)_(m) (m>0) can be used. Here, M representsone or more metal elements selected from Zn, Ga, Al, Mn, and Co.Specifically, M may be Ga, Ga and Al, Ga and Mn, Ga and Co, or the like.

In particular, when an oxide semiconductor containing indium, an oxidesemiconductor containing indium and gallium, or the like is used, atransistor having favorable electrical characteristics can be formed. Inthis embodiment, an In—Ga—Zn—O film is formed as the oxide semiconductorfilm by a sputtering method.

As the target used for the sputtering method, an oxide target having acomposition ratio of In₂O₃:Ga₂O₃:ZnO=1:1:1 [molar ratio] is used.Alternatively, an oxide target having a composition ratio ofIn₂O₃:Ga₂O₃:ZnO=1:1:2 [molar ratio] may be used.

In the case where an In—Zn—O-based material is used as an oxidesemiconductor, a target to be used has a composition ratio of In:Zn=50:1to 1:2 in an atomic ratio (In₂O₃:ZnO=25:1 to 1:4 in a molar ratio),preferably In:Zn=20:1 to 1:1 in an atomic ratio (In₂O₃:ZnO=10:1 to 1:2in a molar ratio), more preferably In:Zn=1.5:1 to 15:1 in an atomicratio (In₂O₃:ZnO=3:4 to 15:2 in a molar ratio). For example, in a targetused for formation of an In—Zn—O-based oxide semiconductor which has anatomic ratio of In:Zn:O=X:Y:Z, the relation of Z>1.5X+Y is satisfied.

The filling rate of the target is higher than or equal to 90% and lowerthan or equal to 100%, preferably higher than or equal to 95% and lowerthan or equal to 100%. With the use of the target with high fillingrate, a dense oxide semiconductor film can be formed.

As the sputtering gas, a rare gas (typically argon), oxygen, or a mixedgas of a rare gas and oxygen can be used. It is preferable to use ahigh-purity gas from which impurities such as hydrogen, water, ahydroxyl group, and hydride are removed as the sputtering gas.

The oxide semiconductor film is preferably formed while the substrate isheated. The substrate is held in a deposition chamber kept under reducedpressure, and deposition is performed in the state where the substratetemperature is set to a temperature higher than or equal to 100° C. andlower than or equal to 600° C., preferably higher than or equal to 200°C. and lower than or equal to 400° C.; thus, the impurity concentrationin the oxide semiconductor film can be reduced.

In order to remove moisture remaining in the deposition chamber, anentrapment vacuum pump such as a cryopump, an ion pump, or a titaniumsublimation pump is preferably used. As an exhaustion unit, a turbomolecular pump to which a cold trap is added may be used. In thedeposition chamber which is exhausted with a cryopump, a hydrogen atom,a compound containing a hydrogen atom such as water, a compoundcontaining a carbon atom, and the like are exhausted, whereby theimpurity concentration in the oxide semiconductor film formed in thedeposition chamber can be reduced.

As one example of conditions for the film formation, the following isgiven: the distance between the substrate and the target is 100 mm, thepressure is 0.6 Pa, the direct-current (DC) power is 0.5 kW, and theatmosphere is an oxygen atmosphere (the proportion of the oxygen flowrate is 100%). When a pulsed direct-current power source is used, powdersubstances (also referred to as particles or dust) that are generated indeposition can be reduced and the film thickness can be uniform.

Next, by performance of a first photolithography step and an etchingstep, the oxide semiconductor film is processed into an island-shapedoxide semiconductor layer 403 (see FIG. 5A).

Note that a resist mask used in the photolithography step may be formedby an inkjet method. Formation of the resist mask by an inkjet methodneeds no photomask; thus, manufacturing cost can be reduced.

Here, the etching of the oxide semiconductor film may be either dryetching or wet etching. Alternatively, both of them may be used. As anetchant used for wet etching of the oxide semiconductor film, forexample, a mixed solution of phosphoric acid, acetic acid, and nitricacid, or the like can be used. Alternatively, ITO-07N (produced by KANTOCHEMICAL CO., INC.) may be used.

Next, dehydration or dehydrogenation of the oxide semiconductor layer403 is performed through heat treatment. In this specification, the term“dehydration or dehydrogenation” refers to not only elimination of wateror a hydrogen molecule but also elimination of a hydrogen atom, ahydroxyl group, or the like.

Through this heat treatment, excessive hydrogen (including water and ahydroxyl group) is removed and a structure of the oxide semiconductorlayer is improved, resulting in less impurity levels in an energy gap.The temperature of the heat treatment is higher than or equal to 250° C.and lower than or equal to 650° C., preferably higher than or equal to350° C. and lower than or equal to 500° C., more preferably higher thanor equal to 390° C. and lower than or equal to 460° C. Note that thelength of time of the heat treatment may be about 1 hour as long as thetemperature is in the above favorable range. The heat treatment may beperformed through rapid thermal annealing (RTA) treatment in anatmosphere of an inert gas (such as nitrogen, helium, neon, or argon) ata temperature of higher than or equal to 500° C. and lower than or equalto 750° C. (or a temperature lower than or equal to the strain point ofthe glass substrate) for approximately more than or equal to 1 minuteand less than or equal to 10 minutes, preferably at 650° C. forapproximately more than or equal to 3 minutes and less than or equal to6 minutes. A method for the heat treatment may be determined by thepractitioner as appropriate. Note that the timing of heat treatment forthe dehydration or dehydrogenation of the oxide semiconductor layer 403is not limited to this timing and may be performed plural times, forexample, before and after a photolithography step or a film formationprocess. In that case, heat treatment in an atmosphere containing oxygenmay be performed.

The heat treatment performed on the oxide semiconductor may be performedon the oxide semiconductor film which has not yet been processed intothe island-shaped oxide semiconductor layer. In that case, after theheat treatment, a photolithography step is performed. The heat treatmentmay be performed after the source electrode layer and the drainelectrode layer are formed over the island-shaped oxide semiconductorlayer as long as the oxide semiconductor is deposited.

Next, a conductive film to be a source electrode layer and a drainelectrode layer (including a wiring formed in the same layer as thesource electrode layer and the drain electrode layer) is formed over theinsulating layer 437 and the oxide semiconductor layer 403. As theconductive film serving as the source electrode layer and the drainelectrode layer, for example, a metal film containing an elementselected from aluminum, chromium, copper, tantalum, titanium,molybdenum, or tungsten, or a metal nitride film containing any of theabove elements as its component (e.g., a titanium nitride film, amolybdenum nitride film, or a tungsten nitride film) can be used.Alternatively, a film of a high-melting-point metal such as titanium,molybdenum, or tungsten or a nitride film of any of them (e.g., atitanium nitride film, a molybdenum nitride film, or a tungsten nitridefilm) may be provided on one surface or both surfaces of a metal filmsuch as an aluminum film or a copper film to form the conductive filmserving as the source electrode layer and the drain electrode layer.

Alternatively, the conductive film serving as the source electrode layerand the drain electrode layer may be formed using a conductive metaloxide. As the conductive metal oxide, indium oxide (In₂O₃), tin oxide(SnO₂), zinc oxide (ZnO), indium tin oxide (In₂O₃—SnO₂; abbreviated toITO), indium zinc oxide (In₂O₃—ZnO), or any of these metal oxidematerials in which silicon oxide is contained can be used.

Next, a resist mask is formed over the conductive film in a secondphotolithography step and selective etching is performed, so that thesource electrode layer 405 a and the drain electrode layer 405 b areformed. Then, the resist mask is removed (see FIG. 5B).

Note that the etching of the conductive film is performed so that theoxide semiconductor layer 403 is not etched as much as possible.However, it is difficult to obtain etching conditions under which onlythe conductive film is etched. In some cases, the oxide semiconductorlayer 403 is partly etched so as to have a groove portion (a recessedportion) by the etching of the conductive film.

In this embodiment, a titanium film is used as the conductive film andan In—Ga—Zn—O-based oxide semiconductor is used as the oxidesemiconductor layer 403, and therefore, the conductive film isselectively etched by using ammonium hydrogen peroxide (a mixture ofammonia, water, and hydrogen peroxide) as an etchant.

Next, the gate insulating layer 402 is formed over the source electrodelayer 405 a, the drain electrode layer 405 b, and the oxidesemiconductor layer 403 (see FIG. 5C). The gate insulating layer 402 canbe formed using any of silicon oxide, silicon nitride, siliconoxynitride, silicon nitride oxide, aluminum oxide, aluminum nitride,aluminum oxynitride, aluminum nitride oxide, hafnium oxide, and galliumoxide, or a mixed material thereof by a plasma CVD method, a sputteringmethod, or the like. The structure of the gate insulating layer 402 isnot limited to a single-layer structure, and may be a layered structureof a plurality of the above materials.

It is preferable that an insulating material containing the same kind ofcomponent as the oxide semiconductor layer be used for the gateinsulating layer 402. Such a material enables the state of the interfacewith the oxide semiconductor layer to be kept well. Here, containing“the same kind of component as the oxide semiconductor layer” meanscontaining one or more elements selected from constituent elements ofthe oxide semiconductor layer. For example, in the case where the oxidesemiconductor layer is formed using an In—Ga—Zn—O-based oxidesemiconductor material, gallium oxide or the like is given as such aninsulating material containing the same kind of component as the oxidesemiconductor layer.

For formation of the gate insulating layer 402, it is preferable toemploy a high density plasma CVD method using microwaves (for example,with a frequency of 2.45 GHz) by which a high-quality insulating layerwhich is dense and has high withstand voltage can be formed. The oxidesemiconductor layer is formed in close contact with the high-qualitygate insulating layer, whereby interface state density at the interfacecan be reduced.

Moreover, it is possible to use as the gate insulating layer aninsulating layer whose quality and characteristics of the interface withthe oxide semiconductor layer are improved by heat treatment performedafter the formation of the insulating layer. In any case, the gateinsulating layer 402 is preferably formed using an insulating layer thatcan reduce the interface state density with the oxide semiconductorlayer to form a favorable interface, as well as having favorable filmquality.

Next, after the conductive film is formed, the gate electrode layer 401is formed through a third photolithography step and an etching step (seeFIG. 5D).

The gate electrode layer 401 can be formed using a metal material suchas molybdenum, titanium, tantalum, tungsten, aluminum, copper,neodymium, or scandium, or an alloy material which includes any of thesemetal materials as a main component by a sputtering method or the like.The structure of the gate electrode layer 401 is not limited to asingle-layer structure, and may be a layered structure of a plurality ofthe above materials.

Next, an insulating film is formed as the insulating layer 407. As theinsulating film, an inorganic insulating film such as a silicon oxidefilm, a silicon oxynitride film, an aluminum oxide film, an aluminumoxynitride film, or a gallium oxide film or a gallium aluminum oxidefilm represented by Ga_(x)Al_(2-x)O_(3+y) (0≦x≦2, y>0, x is more than orequal to 0 and less than or equal to 2, and y is more than 0) can beused.

Although not illustrated, a protective insulating layer for increasingreliability may be formed over the insulating layer 407. As theprotective insulating layer, an inorganic insulating film such as asilicon nitride film, an aluminum nitride film, a silicon nitride oxidefilm, or an aluminum nitride oxide film can be used.

A planarization insulating film may be formed over the insulating layer407 or the protective insulating layer in order to reduce surfaceroughness caused by a transistor. For the planarization insulating film,an organic material such as polyimide, acrylic, or benzocyclobutene canbe used. Other than such organic materials, it is also possible to use alow dielectric constant material (a low-k material) or the like. Notethat the planarization insulating film may be formed by stacking aplurality of insulating films formed from these materials.

Through the above-described process, the transistor 440 is formed.

Next, a measurement system for examination of photoresponsecharacteristics of the manufactured transistors will be described.

A conceptual diagram of the measurement system is illustrated in FIG. 8.A transistor 505 set inside a chamber 508 is irradiated with light whoselight source is a xenon lamp 501 through an optical filter 502, anoptical fiber 503, a rod lens 504, and a light introducing window 509.Here, light 510 for irradiation is spectrally distributed to have acentral wavelength of 400 nm (half width: 10 nm) with the use of theoptical filter 502 (see FIG. 10). As an ammeter 506, a semiconductorparameter analyzer (4155C produced by Agilent Technologies, Inc.) isused, and changes in photoelectric current output from the transistor505 is measured over time and output to a personal computer 507.

At the time of measurement of photoelectric current, the drain voltageof the transistor is 0.1 V, the gate voltage is 0 V, the samplinginterval of the semiconductor parameter analyzer is 1 second, the numberof times of sampling is 3601 (per 1 hour), and the integral action timeis “medium” (1 second).

As described above, three types of transistors are used for themeasurement, and one (hereinafter referred to as Bottom-gate 1) of thebottom-gate transistors is a transistor which is not subjected to heattreatment for the dehydration or dehydrogenation of the oxidesemiconductor layer in the above-described process for manufacturing thetransistor. The other one (hereinafter referred to as Bottom-gate 2) ofthe bottom-gate transistors and the top-gate transistor (hereinafterreferred to as Top-gate) are subjected to heat treatment in which an RTAtreatment at 650° C. and a heating step at 450° C. in a dry air areperformed.

FIG. 11 shows current-time (I−t) characteristics of the threetransistors when irradiation with light having a central wavelength of400 nm with an irradiation intensity of 3.5 mW/cm² is performed for 600seconds. FIG. 12 shows an enlarged graph of a region where current fallsafter the light irradiation. Note that the light irradiation isperformed so that a channel formation region is irradiated with light;thus, for the bottom-gate transistors, light was emitted from sidesprovided with the transistors, and for the top-gate transistor, lightwas emitted from the substrate side.

Bottom-gate 1 has the largest maximum value of photoelectric current(I_(max)) right before the light irradiation is stopped, followed byBottom-gate 2 and Top-gate. Bottom-gate 1 and Bottom-gate 2 aredifferent from each other in that heat treatment for the dehydration ordehydrogenation is performed or not; thus, it is indicated that atransistor including a highly purified oxide semiconductor layer has asmall number of levels which generate photoelectric current. Inaddition, Top-gate has not only a small I_(max) but also highphotoresponse speed. It is found that the current value converges withinapproximately 300 seconds after light irradiation is stopped. Table 2shows τ₁ and τ₂ of each of the transistors.

TABLE 2 I_(max) [A] τ₁ [sec] τ₂ [sec] Bottom-gate 1 3.20E−10 6.1 3821Bottom-gate 2 9.00E−11 3.8 1253 Top-gate 5.00E−12 2.1 —

FIG. 13 shows changes in threshold voltages when voltage is applied sothat a stress of −2 MV/cm is applied to gates at room temperature whilethe transistors are irradiated with light with an illuminance of 360001× with the use of a white LED. Note that source and drain terminals areat GND potentials during the voltage application. Here, Top-gate has thesmallest changes in threshold voltage, followed by Bottom-gate 2 andBottom-gate 1. Similarly, Top-gate has the smallest photoelectriccurrent values in Table 2 and the highest photoresponse speed, followedby Bottom-gate 2 and Bottom-gate 1. Therefore, a top-gate structure issuitable for a transistor including an oxide semiconductor layer interms of reliability.

It is known that when an oxide typified by silicon oxide is irradiatedwith intense ultraviolet rays, electron-hole pairs are generated. Inaddition, it is also known, from C−t measurement under light or thelike, that when an electric field is applied in the above state,electrons and holes are separated from each other to become freecarriers. It is said that in silicon oxide, holes generated by lightirradiation are moved very slowly and trapped by hole traps existing inthe oxide film to be stable charge. An In—Ga—Zn—O film has a relativelywide band gap, which is 3.1 eV. Owing to such a structure, mobility ofholes is extremely lower than that of electrons. In the above-describedphotoresponse characteristics, carriers are increased by irradiating theIn—Ga—Zn—O film even with light having a wavelength of 400 nm, and thereare a long relaxation time and a short relaxation time. These resultscan be seen in a quite similar manner to that in physics of siliconoxide.

Photoresponse characteristics of an In—Ga—Zn—O semiconductor will bediscussed on the assumption that the In—Ga—Zn—O semiconductor has bandmodels as illustrated in FIG. 14. The two-stage relaxation time ofcarriers, which is τ₁ and τ₂, is seen in the graph of the photoelectriccurrent because there are two kinds of trap levels: an electron traplevel, which is a shallow level close to a conduction band, and a holetrap level, which is a deep level close to a valence band. The formershallow electron trap level relates to the rapid response time τ₁, andthe latter deep hole trap level relates to the slow response time τ₂. Ifthere were only the former shallow electron trap level, a very rapidresponse converging in approximately several seconds would be assumed;as a result, changes in threshold voltages of transistors would notoccur. Suppose the deep hole trap level exists, trapped holes do noteasily return to the valence band, resulting in a very slow response.The trapped charge remains in the film as fixed charge; as a result,changes in threshold voltages of transistors occur. Therefore, atransistor including an oxide semiconductor desirably has a relaxationtime in which τ₁<τ₂ is satisfied and τ₂ is short.

It is indicated that in a transistor including an oxide semiconductorlayer, which is one embodiment of the present invention, the density ofdeep hole trap levels close to a valence band in an energy gap can bereduced depending on a structure or a process for manufacturing thetransistor; therefore, it is possible to manufacture a transistor inwhich light deterioration is suppressed as much as possible andelectrical characteristics are stable. Thus, reliability of asemiconductor device such as a display device including the transistorcan be increased.

This embodiment can be implemented in appropriate combination withstructures described in the other embodiment.

Embodiment 2

A semiconductor device disclosed in this specification can be applied toa variety of electronic devices (including amusement machines). Examplesof electronic devices are a television set (also referred to as atelevision or a television receiver), a monitor of a computer or thelike, a camera such as a digital camera or a digital video camera, adigital photo frame, a mobile phone handset (also referred to as amobile phone or a mobile phone device), a portable game machine, aportable information terminal, an audio reproducing device, a large gamemachine such as a pachinko machine, and the like. Examples of electronicdevices each including the transistor and a semiconductor deviceincluding the transistor described in the above embodiment will bedescribed.

FIG. 15A illustrates an electronic book reader (also referred to as ane-book reader) which can include housings 9630, a display portion 9631,operation keys 9632, a solar cell 9633, and a charge and dischargecontrol circuit 9634. The electronic book reader illustrated in FIG. 15Ahas a function of displaying various kinds of data (e.g., a still image,a moving image, and a text image), a function of displaying a calendar,a date, time, or the like on the display portion, a function ofoperating or editing the data displayed on the display portion, afunction of controlling processing by various kinds of software(programs), and the like. Note that in FIG. 15A, a structure including abattery 9635 and a DCDC converter (hereinafter abbreviated as aconverter) 9636 is illustrated as an example of the charge and dischargecontrol circuit 9634. By applying the semiconductor device described inthe other embodiment to the display portion 9631, the electronic bookreader can be highly reliable.

In the structure of FIG. 15A, a semi-transmissive or reflective liquidcrystal display device is used for the display portion 9631, whereby theelectronic book reader is excellent in visibility even in a relativelybright environment. In such an environment, power generation by thesolar cell 9633 and charge with the battery 9635 can be efficientlyperformed. Note that the solar cell 9633 can be provided in not only theillustrated region but also a space (a surface or a rear surface) of thehousing 9630 as appropriate. When a lithium ion battery is used as thebattery 9635, there is an advantage of downsizing or the like.

The structure and the operation of the charge and discharge controlcircuit 9634 illustrated in FIG. 15A will be described with reference toa block diagram in FIG. 15B. The solar cell 9633, the battery 9635, theconverter 9636, a converter 9637, switches SW1 to SW3, and the displayportion 9631 are shown in FIG. 15B. The battery 9635, the converter9636, the converter 9637, and the switches SW1 to SW3 are included inthe charge and discharge control circuit 9634.

First, an example of operation in the case where power is generated bythe solar cell 9633 using external light is described. The voltage ofpower generated by the solar cell is raised or lowered by the converter9636 to a suitable voltage for charging the battery 9635. Then, when thepower from the solar cell 9633 is used for the operation of the displayportion 9631, the switch SW1 is turned on and the voltage of the poweris raised or lowered by the converter 9637 so as to be a voltage neededfor the display portion 9631. In addition, when display on the displayportion 9631 is not performed, the switch SW1 is turned off and a switchSW2 is turned on so that charge of the battery 9635 may be performed.

Next, operation in the case where power is not generated by the solarcell 9633 owing to lack of external light is described. The voltage ofpower accumulated in the battery 9635 is raised or lowered by theconverter 9637 by turning on the switch SW3. Then, power from thebattery 9635 is used for the operation of the display portion 9631.

Note that the solar cell is described as one example of a means forcharging, the battery 9635 may be charged with another means or with acombination of the solar cell and another means.

FIG. 16A illustrates a laptop personal computer including a main body3001, a housing 3002, a display portion 3003, a keyboard 3004, and thelike. By applying the semiconductor device described in the otherembodiment to the display portion 3003, the laptop personal computer canbe highly reliable.

FIG. 16B illustrates a personal digital assistant (PDA) including adisplay portion 3023, an external interface 3025, an operation button3024, and the like in a main body 3021. A stylus 3022 is included as anaccessory for operation. By applying the semiconductor device describedin the other embodiment to the display portion 3023, the personaldigital assistant (PDA) can be highly reliable.

FIG. 16C illustrates an example of an electronic book reader. Forexample, an electronic book reader 2700 has two housings, a housing 2701and a housing 2703. The housing 2701 and the housing 2703 are combinedwith a hinge 2711. The housing 2701 and the housing 2703 can be openedand closed with the hinge 2711 as an axis, and can operate like a paperbook.

A display portion 2705 and a display portion 2707 are incorporated inthe housing 2701 and the housing 2703, respectively. The display portion2705 and the display portion 2707 may display one image or differentimages. In the structure where different images are displayed on thedisplay portion 2705 and the display portion 2707, for example, theright display portion (the display portion 2705 in FIG. 16C) can displaytext and the left display portion (the display portion 2707 in FIG. 16C)can display images. By applying the semiconductor device described inthe other embodiment to the display portions 2705 and 2707, theelectronic book reader 2700 can be highly reliable.

FIG. 16C illustrates an example in which the housing 2701 is providedwith an operation portion and the like. For example, the housing 2701 isprovided with a power switch 2721, operation keys 2723, a speaker 2725,and the like. With the operation keys 2723, pages can be turned. Notethat a keyboard, a pointing device, or the like may also be provided onthe surface of the housing, on which the display portion is provided.Furthermore, an external connection terminal (an earphone terminal, aUSB terminal, or the like), a recording medium insertion portion, andthe like may be provided on the back surface or the side surface of thehousing. Moreover, the electronic book reader 2700 may have a functionof an electronic dictionary.

The electronic book reader 2700 may have a configuration capable ofwirelessly transmitting and receiving data. Through wirelesscommunication, desired book data or the like can be purchased anddownloaded from an electronic book server.

FIG. 16D illustrates a portable information terminal, which includes twohousings, a housing 2800 and a housing 2801. The housing 2801 includes adisplay panel 2802, a speaker 2803, a microphone 2804, a pointing device2806, a camera 2807, an external connection terminal 2808, and the like.In addition, the housing 2800 includes a solar battery 2810 having afunction of charge of the portable information terminal, an externalmemory slot 2811, and the like. Further, an antenna is incorporated inthe housing 2801. By applying the semiconductor device described in theother embodiment to the display panel 2802, the portable informationterminal can be highly reliable.

Further, the display panel 2802 is provided with a touch panel. Aplurality of operation keys 2805 which are displayed as images areillustrated by dashed lines in FIG. 16D. Note that a booster circuit ismounted for boosting a voltage output from the solar battery 2810 to avoltage needed for each circuit.

In the display panel 2802, the display direction can be appropriatelychanged depending on a usage pattern. Further, the camera 2807 isprovided in the same plane as the display panel 2802, and thus theportable information terminal can be used for videophone calls. Thespeaker 2803 and the microphone 2804 can be used for voice recording,playback, and the like as well as voice calls. Furthermore, the housings2800 and 2801 which are developed as illustrated in FIG. 16D can overlapwith each other by sliding; thus, the size of the portable informationterminal can be decreased, which makes the portable information terminalsuitable for being carried.

The external connection terminal 2808 can be connected to various typesof cables such as a charging cable and a USB cable, and charge and datacommunication with a personal computer or the like are possible.Further, a large amount of data can be handled by insertion of ahigh-capacity storage medium into the external memory slot 2811.

Further, in addition to the above functions, an infrared communicationfunction, a television reception function, or the like may be provided.

FIG. 16E illustrates a digital video camera including a main body 3051,a display portion A 3057, an eyepiece 3053, an operation switch 3054, adisplay portion B 3055, a battery 3056, and the like. By applying thesemiconductor device described in the other embodiment to the displayportion A 3057 and the display portion B 3055, the digital video cameracan be highly reliable.

FIG. 16F illustrates an example of a television set. In the televisionset 9600, a display portion 9603 is incorporated in a housing 9601. Thedisplay portion 9603 can display images. Here, the housing 9601 issupported by a stand 9605. By applying the semiconductor devicedescribed in the other embodiment to the display portion 9603, thetelevision set 9600 can be highly reliable.

The television set 9600 can be operated by an operation switch of thehousing 9601 or a separate remote controller. Further, the remotecontroller may be provided with a display portion for displaying dataoutput from the remote controller.

Note that the television set 9600 is provided with a receiver, a modem,and the like. With the use of the receiver, general televisionbroadcasting can be received. Moreover, when the display device isconnected to a communication network with or without wires via themodem, one-way (from a sender to a receiver) or two-way (between asender and a receiver or between receivers) information communicationcan be performed.

This embodiment can be implemented in appropriate combination with thestructures described in the other embodiment.

This application is based on Japanese Patent Application serial no.2010-144694 filed with Japan Patent Office on Jun. 25, 2010, the entirecontents of which are hereby incorporated by reference.

1. A transistor comprising: an oxide semiconductor layer to be a channelformation region, wherein, after the oxide semiconductor layer isirradiated with light and the light is turned off, a relaxation time ofcarriers in photoresponse characteristics of the oxide semiconductorlayer has at least two kinds of modes: τ₁ and τ₂, wherein τ₁<τ₂ issatisfied, and wherein τ₂ is 300 seconds or less.
 2. The transistoraccording to claim 1, wherein the oxide semiconductor layer comprises atleast one of In, Zn, and Ga.
 3. The transistor according to claim 1,wherein a light source of the light is a white LED.
 4. The transistoraccording to claim 1, wherein the light has a central wavelength of 400nm.
 5. The transistor according to claim 1, wherein the oxidesemiconductor layer has a first trap level close to a conduction bandand a second trap level close to a valence band.
 6. A transistorcomprising: an oxide semiconductor layer to be a channel formationregion; a source electrode layer and a drain electrode layer overlappingwith a part of the oxide semiconductor layer; a gate insulating layeroverlapping with the oxide semiconductor layer, the source electrodelayer, and the drain electrode layer; and a gate electrode overlappingwith a part of the oxide semiconductor layer with the gate insulatinglayer provided therebetween, wherein, after the oxide semiconductorlayer is irradiated with light and the light is turned off, a relaxationtime of carriers in photoresponse characteristics of the oxidesemiconductor layer has at least two kinds of modes: τ₁ and τ₂, whereinτ₁<τ₂ is satisfied, and wherein τ₂ is 300 seconds or less.
 7. Thetransistor according to claim 6, wherein the oxide semiconductor layercomprises at least one of In, Zn, and Ga.
 8. The transistor according toclaim 6, wherein a light source of the light is a white LED.
 9. Thetransistor according to claim 6, wherein the light has a centralwavelength of 400 nm.
 10. The transistor according to claim 6, whereinthe oxide semiconductor layer has a first trap level close to aconduction band and a second trap level close to a valence band.
 11. Thetransistor according to claim 6, wherein the gate insulating layercontains one or more elements selected from constituent elements of theoxide semiconductor layer.
 12. A semiconductor device comprising: atransistor comprising an oxide semiconductor layer to be a channelformation region, wherein, after the oxide semiconductor layer isirradiated with light and the light is turned off, a relaxation time ofcarriers in photoresponse characteristics of the oxide semiconductorlayer has at least two kinds of modes: τ₁ and τ₂, wherein τ₁, <τ₂ issatisfied, and wherein τ₂ is 300 seconds or less.
 13. The semiconductordevice according to claim 12, wherein the oxide semiconductor layercomprises at least one of In, Zn, and Ga.
 14. The semiconductor deviceaccording to claim 12, wherein a light source of the light is a whiteLED.
 15. The semiconductor device according to claim 12, wherein thelight has a central wavelength of 400 nm.
 16. The semiconductor deviceaccording to claim 12, wherein the oxide semiconductor layer has a firsttrap level close to a conduction band and a second trap level close to avalence band.
 17. The semiconductor device according to claim 12,wherein the semiconductor device is applicable to an electronic device.18. A semiconductor device comprising: a transistor comprising: an oxidesemiconductor layer to be a channel formation region; a source electrodelayer and a drain electrode layer overlapping with a part of the oxidesemiconductor layer; a gate insulating layer overlapping with the oxidesemiconductor layer, the source electrode layer, and the drain electrodelayer; and a gate electrode overlapping with a part of the oxidesemiconductor layer with the gate insulating layer providedtherebetween, wherein, after the oxide semiconductor layer is irradiatedwith light and the light is turned off, a relaxation time of carriers inphotoresponse characteristics of the oxide semiconductor layer has atleast two kinds of modes: τ₁ and τ₂ wherein τ₁<τ₂ is satisfied, andwherein τ₂ is 300 seconds or less.
 19. The semiconductor deviceaccording to claim 18, wherein the oxide semiconductor layer comprisesat least one of In, Zn, and Ga.
 20. The semiconductor device accordingto claim 18, wherein a light source of the light is a white LED.
 21. Thesemiconductor device according to claim 18, wherein the light has acentral wavelength of 400 nm.
 22. The semiconductor device according toclaim 18, wherein the oxide semiconductor layer has a first trap levelclose to a conduction band and a second trap level close to a valenceband.
 23. The semiconductor device according to claim 18, wherein thegate insulating layer contains one or more elements selected fromconstituent elements of the oxide semiconductor layer.
 24. Thesemiconductor device according to claim 18, wherein the semiconductordevice is applicable to an electronic device.